2007 Kyoto Prize Laureates

Advanced Technology

Materials Science and Engineering

Hiroo Inokuchi

/  Chemist

1927 - 2014

Professor Emeritus, The University of Tokyo and Institute for Molecular Science/National Institutes of Natural Sciences

Commemorative Lectures

My Journey in Chemical Research—Learning from People and Things

2007

11 /11 Sun

Place:Kyoto International Conference Center

Workshop

New Developments in Organic Semiconductors and Conductors

2007

11 /12 Mon

13:00 - 17:10

Place:Kyoto International Conference Center

Achievement Digest

Pioneering and Fundamental Contributions to Organic Molecular Electronics

Dr. Hiroo Inokuchi initiated pioneering research on electrical conduction between molecules with benzene rings and established the scientific foundation for studying the electrical conductivity of organic materials. Further, he systematically elucidated an electronic structure of a wide variety of organic materials by photoelectron spectroscopy. Through a series of such studies, he established the academic base essential for studying the electronic properties, making fundamental contributions to the subsequent development of organic molecular electronics.

Citation

Dr. Hiroo Inokuchi focused his attention on organic molecules consisting of benzene rings in the late 1940s and started pioneering research on electrical conduction between molecules, discovering that they exhibit semiconducting properties. Further, he established the scientific foundation for studying the electrical conductivity of organic materials through his discovery that the addition of an electron-accepting substance to organic molecules dramatically increases electrical conductivity, making them an organic conductor. Moreover, Dr. Inokuchi systematically elucidated the electronic structure of a wide variety of organic materials by photoelectron spectroscopy. Through a series of such studies, Dr. Inokuchi established the scientific foundation essential for understanding and utilizing the electronic properties and functions of organic materials, making fundamental contributions to the subsequent development of organic molecular electronics.

Around 1950, Dr. Inokuchi, jointly with Dr. Hideo Akamatu, conducted groundbreaking studies that systematically investigated the intermolecular electrical conductivity of an organic molecule called violanthrone consisting of nine benzene rings, and found that this organic material is capable of acting like a semiconductor in a manner similar to inorganic materials. In addition, he discovered jointly with Dr. Akamatu and Dr. Yoshio Matsunaga that the addition of an electron-accepting substance such as bromine or iodine to an organic material such as perylene causes transfer of electrons between the two components and forms charge-transfer complexes with high charge density, thereby increasing electrical conductivity significantly. These pioneering studies triggered major advances in the science of organic conductors in the following 50 years, helping to establish a technological basis for the practical utilization of organic conductors. Dr. Inokuchi continued with systematic studies of photoelectron spectroscopy to elucidate the electronic structures of organic materials, determining the ionization energies of a large number of organic materials. The findings of this research played a critical role in the design and creation of organic electroluminescent (EL) devices in later years.

Dr. Inokuchi’s groundbreaking studies served as a basis not only for scientific investigations into organic conductors, which have advanced remarkably over the past fifty years, but also for the creation and development of technologies that utilize the electronic properties of organic materials, making fundamental contributions to the establishment of organic molecular electronics that includes applications to organic EL devices and organic transistors. Furthermore, Dr. Inokuchi has assisted in the development of outstanding researchers and research groups in the science and engineering fields of organic molecules and established a world-class center of excellence for the research of organic materials with electrical properties, making substantial contributions to international, academic interactions.

For these reasons, the Inamori Foundation is pleased to present the 2007 Kyoto Prize in Advanced Technology to Dr. Hiroo Inokuchi.

Profile

Biography
1927
Born in Hiroshima, Japan
1950
Research Associate, School of Science, The University of Tokyo (1955-1957 Ramsay Fellow, The University of Nottingham)
1956
D.Sc., The University of Tokyo
1959
Associate Professor, School of Science, The University of Tokyo
1960
Associate Professor, Institute for Solid State Physics, The University of Tokyo
1967
Professor, Institute for Solid State Physics, The University of Tokyo
1975
Professor Emeritus, The University of Tokyo
1975
Professor, Institute for Molecular Science, Okazaki National Research Institute
1987
Director General, Institute for Molecular Science, Okazaki National Research Institute
1993
President, Okazaki National Research Institute
1995
Emeritus Professor, Institute for Molecular Science, Okazaki National Research Institute (currently National Institutes of Natural Sciences)
1996
Chief Scientist, Space Utilization Research Programme, National Space Development Agency of Japan (NASDA)
2001
Academic Counselor, International Institute for Advanced Studies
2003
Consultant to the President, Japan Aerospace Exploration Agency
2005
Distinguished Consultant, Institute for Molecular Science, National Institutes of Natural Sciences
2006
Chairman, Japan Space Forum
Selected Awards and Honors
1965
Japan Academy Prize, The Japan Academy
1978
The Chemical Society of Japan Award, The Chemical Society of Japan
1989
Fujihara Award, The Fujihara Foundation of Science
1994
Person of Cultural Merit, Japan
2001
Order of Culture, Japan
Member
The Japan Academy, The Chinese Academy of Science
Selected Publications
1950
On the Electrical Conductibity of Violanthrone, Iso-Violanthrone and Pyranthrone, The Journal of Chemical Physics 18: 810-811 (Akamatsu, H. and Inokuchi, H.), 1950.
1954
Photoconductivity of Condensed Polynuclear Aromatic Compounds, Bulletin of the Chemical Society of Japan 27: 22-27, 1954.
1954
Electrical Conductivity of the Perylene-Bromine Complex, Nature 173: 168-169 (Akamatu, H., Inokuchi, H. and Matsunaga, Y.), 1954.
1961
Electrical Conductivity of Organic Semiconductors, Solid State Physics 12: 93-148 (with Akamatsu, H.), 1961.
1964
"Organic Semiconductors", Maki Shoten Publishing Co., p.201. (in Japanese), 1964.
1986
A Novel Type of Organic Semiconductors. Molecular Fastener. Chemistry Letters : 1263-1266 (with Saito, G., Wu, P., Seki, K., Tang, T.B., Mori, T., Imaeda, K., Enoki, T., Higuchi, Y., Inaka, K. and Yasuoka, N.), 1986.

Profile is at the time of the award.

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